A micellar catalytic system for chemoselective aerobic oxidation of primary alcohol in the diol fragment guaiacylglycerol-guaiacyl ether as one of the most common structure in lignin has been proposed. The catalyst system consists of TEMPO/Cu (II), mediated by oxygen gas. Our studies highlight the prospect of combining this method with a PEO-PPO-PEO micellar system in basic aqueous effluent of delignification processes of lignocellulosic materials to achieve the oxidation of primary alcohol to aldehyde.
Metrics
35 File views/ downloads
90 Record Views
Details
Title
Chemoselective aerobic oxidation of aliphatic alcohols in lignin in micellar system
Creators
Mohammadali Azadfar (Author)
William C. Hiscox (Author)
Shulin Chen (Author)
Conference
Washington State University Academic Showcase (Pullman, Washington )
Academic Unit
NMR Center; Biological Systems Engineering, Department of; WSU Academic Showcase 2017
Identifiers
99900501964701842
Copyright
In copyright ; openAccess ; http://rightsstatements.org/vocab/InC/1.0/ ; http://purl.org/eprint/accessRights/OpenAccess