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Rights Statements InC/1.0 , Open Access
Conference proceeding
Magnetically Induced Circular Polarization of Emission: Application to Inorganic Complexes
Vol.17, pp.176-179
Society of Photo‑Optical Instrumentation Engineers
1978
Handle:
https://hdl.handle.net/2376/16886
Abstract
A sensitive spectrometer for the measurement of circular polarization of emission, utilizing a photoelastic modulator, is presented. This spectrometer, when augmented by a superconducting magnet and dewar assembly, provides an excellent system for studying magnetically induced circular polarization of emission (MICE). In order to exemplify both the system and the usefulness of MICE, a partial analysis of the MICE observed from Ru(4,7diphenyl- 1,10- phenanthroline)3C12 dispersed in a polymethylmethacrylate (PMM) matrix in the 2 to 100 °K temperature range is reported. Also presented is a discussion of the effects of photoselection on the observed MICE for these D3 symmetry complexes. It is found that MICE is more sensitive to the detailed nature of the levels involved in emission than a combination of zero field techniques. MICE should prove to be an exceptionally useful tool for probing excited states of inorganic complexes.
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Details
- Title
- Magnetically Induced Circular Polarization of Emission: Application to Inorganic Complexes
- Creators
- K. W. Hipps (Author)G. A. Crosby (Author)
- Publication Details
- Vol.17, pp.176-179
- Conference
- Society of Photo‑Optical Instrumentation Engineers
- Academic Unit
- Chemistry, Department of; Mechanical and Materials Engineering, School of
- Identifiers
- 99900501058401842
- Copyright
- In copyright ; openAccess ; http://rightsstatements.org/vocab/InC/1.0/ ; http://purl.org/eprint/accessRights/OpenAccess
- Language
- English
- Resource Type
- Conference proceeding