Dissertation
Using Thermomechanical and Photomechanical Characterization to Study the Microscopic Mechanism of Light Actuation in Polymeric Materials
Washington State University
Doctor of Philosophy (PhD), Washington State University
2022
DOI:
https://doi.org/10.7273/000005284
Abstract
Shape-changing photomechanical materials that are responsive to physical stimuli such as light, stress, and heat are the main focus of this dissertation. Such materials are of interest due to their novel properties and potential applications. We seek to understand the underlying mechanism of their response by designing new experiments and models that can differentiate between the proposed mechanisms. They include photothermal heating, photoisomerization, and photoreorientation. This dissertation studies the photomechanical and thermomechanical responses in dye-doped fibers and thin films as a function of time, temperature, intensity, and light polarization-dependent to provide inputs to theoretical models that decouple the contributing mechanisms. This leads to an understanding of how changes at the molecular level affect the bulk photomechanical response. The figure of merit, which quantifies the efficiency of the photomechanical material in converting light energy into work, is also defined and measured to compare the efficiency of the materials under various conditions. The microscopic response of a photomechanical materials originates in the photomorphon, which is the smallest part of the material that behaves as the bulk. In dye-doped polymers, the photomorphon consists of a photoactive molecule and the host polymer, which acts as a passive environment. We model the photoreological properties of dye-doped polymers as springs whose properties can change in response to light. A measure of the temperature and intensity dependent stress and Young’s modulus characterizes the parameters that relate the microscopic response to the bulk response in the materials. We build an understanding of the dependence of the photomechanical response of polymeric materials on factors such as types of dyes and their concentrations, light intensity and polarization, and temperature that can be used as a guide for making improved photomechanical materials that will find applications that require smart shape shifting materials.
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Details
- Title
- Using Thermomechanical and Photomechanical Characterization to Study the Microscopic Mechanism of Light Actuation in Polymeric Materials
- Creators
- Zoya Ghorbanishiadeh
- Contributors
- Mark Kuzyk (Advisor)Fred Gittes (Committee Member)Brian Collins (Committee Member)
- Awarding Institution
- Washington State University
- Academic Unit
- Physics and Astronomy, Department of
- Theses and Dissertations
- Doctor of Philosophy (PhD), Washington State University
- Publisher
- Washington State University
- Number of pages
- 233
- Identifiers
- 99901019840701842
- Language
- English
- Resource Type
- Dissertation