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CC BY V4.0, Open Access
Thesis
CADMIUM TELLURIDE: A STUDY ON THE EFFECTS OF IODINE DOPING
Washington State University
Master of Science (MS), Washington State University
01/2022
DOI:
https://doi.org/10.7273/000004583
Handle:
https://hdl.handle.net/2376/118663
Abstract
In the pursuit of creating efficient CdTe p-n homojunctions, we developed iodine (I) n-type doped CdTe using Cadmium Iodide (CdI2) as a dopant in varying concentrations (1018 cm-3, 1019 cm-3 and 1020 atoms·cm-3 target concentrations) in CdTe. Iodide doped crystals were grown using a Modified Vertical Bridgman furnace (MVB). Single crystals were characterized using XRD (X-Ray Diffraction), Hall effect, IR (Infrared) Microscopy, UV-VIS-NIR (Ultraviolet-Visible-Near infrared Spectroscopy) and FTIR (Fourier Transform Infrared Spectroscopy). Partners at the National Renewable Energy Laboratory (NREL) also provided data for Hall Effect and Two Photon Excitation Time Resolved Photoluminescence (2PE TRPL) of wafers and films. Photoluminescence mapping (PL mapping) was obtained from Klar scientific, and glow discharge mass spectrometry (GDMS) for purity and final doping concentration was obtained from the National Research Council Canada. Due to poor carrier properties in the crystals as-grown, two annealing treatments were explored, in either tellurium or cadmium vapor. Homojunctions were made at NREL by depositing n-type films from these crystals on p-type single crystals, CdTe:P grown and WSU. The n-type films were created using the close-space sublimation epitaxy (CSSE) process. Herein is reported the results of the grown CdTe:I crystals and, to a lesser extent, the properties of the CdTe:I thin films formed by CSSE.
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Details
- Title
- CADMIUM TELLURIDE
- Creators
- Samuel Bigbee-Hansen
- Contributors
- John S McCloy (Advisor)Colin C Merriman (Committee Member)Matthew D McCluskey (Committee Member)
- Awarding Institution
- Washington State University
- Academic Unit
- Voiland College of Engineering and Architecture
- Theses and Dissertations
- Master of Science (MS), Washington State University
- Publisher
- Washington State University
- Number of pages
- 58
- Identifiers
- OCLC#: 1370911377; 99900898740301842
- Language
- English
- Resource Type
- Thesis