Glass-Ceramics Hexaferrites in-situ crystallization Strontium Borate Glass system Mechanical Engineering
Typical glass formers are amorphous in their underlying structure and do not exhibit any form of detectable magnetism. However, the compositional flexibility of such non-crystalline systems enhances the potential for the nucleation and growth of highly magnetic phases producing what is referred to as glass ceramics. Such Magnetic Glass Ceramic (MGC) materials find applications in magnetic storage in recording media, permanent magnets, and dielectric materials. Cancer therapy stands to benefit from non-volatility of crystallized magnetic phases in MGCs as compared to their nanoparticle counterparts. The principal goals of this thesis were to: 1.) Identify and optimize the selection procedure for favorable glass systems by systematic increments in composition. 2.) Characterize glasses based on a down-selection criterion of amorphousness-upon-quench using x-ray diffraction (XRD). 3.) Prepare MGCs via varied heat treatment techniques in the range of 700-900°C and further characterize them for crystallization by differential thermal analysis (DTA) and X-ray diffraction (XRD), magnetic behavior via vibrating sample magnetometry (VSM), and microstructural signatures from scanning electron microscopy (SEM).
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Title
MAGNETIC GLASS CERAMICS: A STUDY OF HEXAFERRITES IN THE STRONTIUM BORATE GLASS SYSTEM
Creators
Arumala Josiah Lere-Adams
Contributors
John S McCloy (Advisor)
David P Field (Committee Member)
Scott P Beckman (Committee Member)
Awarding Institution
Washington State University
Academic Unit
Voiland College of Engineering and Architecture
Theses and Dissertations
Master of Science (MS), Washington State University