Thesis
Molecular design of disubstituted perylene diimides for self-assembly studies
Washington State University
Master of Science (MS), Washington State University
2010
Handle:
https://hdl.handle.net/2376/106452
Abstract
1,7-di(n-butylamino) and 1-bromo-7-(n-butylamino) perylene diimide (PDI) analogues were synthesized by reaction of 1,7-difluoro and 1,7-dibromo PDIs respectively with excess n-butylamine and characterized by NMR and UV-vis spectroscopies. Bathochromic shifts in the S0-S1 UV-vis absorption band for halogen-substituted and alkylamino-substituted PDI pairs were measured. Concentration-dependent chemical shifts for the 1,7-difluoro, 1,7-di(n-butylamino) and 1-bromo-7-(n-butylamino) PDIs were measured using NMR techniques and correlated to their self-assembly characteristics.
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Details
- Title
- Molecular design of disubstituted perylene diimides for self-assembly studies
- Creators
- Duvano Garnes
- Contributors
- Alexander D. Q. Li (Degree Supervisor)
- Awarding Institution
- Washington State University
- Academic Unit
- Chemistry, Department of
- Theses and Dissertations
- Master of Science (MS), Washington State University
- Publisher
- Washington State University; [Pullman, Washington] :
- Identifiers
- 99900525383801842
- Language
- English
- Resource Type
- Thesis