Journal article
15N NMR and electronic properties of S-nitrosothiols
Bioorganic & medicinal chemistry letters, Vol.9(19), pp.2897-2902
1999
Handle:
https://hdl.handle.net/2376/105794
PMID: 10522714
Abstract
Investigation of the 15N NMR of S-nitrosothiols showed that primary and tertiary RSNOs have distinct 15N chemical shifts around 730 and 790 ppm, respectively. Using 15N NMR technique, the equilibrium constant of NO transfer between SNAP and GSH was found to be 0.74. For primary RSNOs, linear relationships exist among 15N NMR chemical shifts, reduction potentials, and the p K as of their parent thiols. 15N NMR for a series of S-nitrosothiols was investigated. Using 15N NMR technique, the equilibrium constant of NO transfer between SNAP and GSH was found to be 0.74. For primary RSNOs, linear relationship exist among 15N chemical shifts, reduction potentials, and p K as of their parent thiols.
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Details
- Title
- 15N NMR and electronic properties of S-nitrosothiols
- Creators
- Kun Wang - Department of Chemistry, Wayne State University, Detroit, MI 48202, U.S.AYongchun Hou - Department of Chemistry, Wayne State University, Detroit, MI 48202, U.S.AWei Zhang - Department of Chemistry, Wayne State University, Detroit, MI 48202, U.S.AMohamad B Ksebati - Department of Chemistry, Wayne State University, Detroit, MI 48202, U.S.AMing Xian - Department of Chemistry, Wayne State University, Detroit, MI 48202, U.S.APeng George Wang - Department of Chemistry, Wayne State University, Detroit, MI 48202, U.S.AJin-Pei Cheng - Nankai University
- Publication Details
- Bioorganic & medicinal chemistry letters, Vol.9(19), pp.2897-2902
- Academic Unit
- Department of Chemistry
- Publisher
- Elsevier Ltd
- Identifiers
- 99900546821401842
- Language
- English
- Resource Type
- Journal article