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A concise [C+NC+CC] coupling-enabled synthesis of kaitocephalin
Journal article

A concise [C+NC+CC] coupling-enabled synthesis of kaitocephalin

Philip Garner, Laksiri Weerasinghe, Ian Van Houten and Jieyu Hu
Chemical communications (Cambridge, England), Vol.50(38), pp.4908-4910
2014
Handle:
https://hdl.handle.net/2376/106031
PMID: 24691728

Abstract

A 15-step synthesis of the iGluR antagonist kaitocephalin from aspartic acid is reported. The linchpin pyrrolidine ring of the target molecule is efficiently assembled with in a single operation via an asymmetric [C+NC+CC] reaction.

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