Journal article
Beyond ketonization: selective conversion of carboxylic acids to olefins over balanced Lewis acid-base pairs
Chemical communications (Cambridge, England), Vol.52(28), pp.4975-4978
04/11/2016
Handle:
https://hdl.handle.net/2376/104721
PMID: 26898532
Abstract
We report the direct conversion of mixed carboxylic acids to C-C olefins with up to 60 mol% carbon yield through cascade (cross) ketonization, (cross) aldolization and self-deoxygenation reactions. Co-feeding hydrogen provides an additional ketone hydrogenation/dehydration pathway to a wider range of olefins.
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Details
- Title
- Beyond ketonization: selective conversion of carboxylic acids to olefins over balanced Lewis acid-base pairs
- Creators
- Rebecca A L Baylon - The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164-2710, USA. junming.sun@wsu.eduJunming Sun - The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164-2710, USA. junming.sun@wsu.eduKevin J Martin - Archer Daniels Midland Company, 1001 N Brush College Road, Decatur, IL 62521, USAPadmesh Venkitasubramanian - Archer Daniels Midland Company, 1001 N Brush College Road, Decatur, IL 62521, USAYong Wang - The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164-2710, USA. junming.sun@wsu.edu and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352, USA. yong.wang@pnnl.gov
- Publication Details
- Chemical communications (Cambridge, England), Vol.52(28), pp.4975-4978
- Academic Unit
- Chemical Engineering and Bioengineering, School of
- Publisher
- England
- Identifiers
- 99900546814301842
- Language
- English
- Resource Type
- Journal article