Journal article
Catalytic hydrodeoxygenation of anisole: an insight into the role of metals in transalkylation reactions in bio-oil upgrading
Green chemistry : an international journal and green chemistry resource : GC, Vol.19(7), pp.1668-1673
2017
Handle:
https://hdl.handle.net/2376/109374
Abstract
Alkylbenzene was observed during continuous hydrodeoxygenation of anisole in toluene. Besides acidic compositions, metals in catalysts play an important role in the transalkylation reaction during the HDO of anisole. Some metals (e.g.NiMo) that enabled partial hydrogenation could temporarily destroy aromaticity, resulting in a high yield of alkylated products. In addition, a high temperature facilitated transalkylation, while temperatures over 400 °C caused severe aromatic condensation.
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Details
- Title
- Catalytic hydrodeoxygenation of anisole: an insight into the role of metals in transalkylation reactions in bio-oil upgrading
- Creators
- Hongliang Wang - Biological Systems Engineering and the Bioproduct Sciences and Engineering Laboratory, Washington State University, Richland, USAMaoqi Feng - Chemistry & Chemical Engineering Division, Southwest Research Institute, San Antonio, USABin Yang - Biological Systems Engineering and the Bioproduct Sciences and Engineering Laboratory, Washington State University, Richland, USA
- Publication Details
- Green chemistry : an international journal and green chemistry resource : GC, Vol.19(7), pp.1668-1673
- Academic Unit
- Biological Systems Engineering, Department of
- Identifiers
- 99900547355701842
- Language
- English
- Resource Type
- Journal article