Journal article
Dy3+-doped yttrium complex molecular crystals for two-color thermometry in heterogeneous materials
Journal of luminescence, Vol.188, pp.238-245
08/01/2017
Abstract
We develop Dy3+-doped yttrium complexes for use as two-color thermometry (TCT) phosphor molecular crystals in heterogeneous materials. These complexes include: Dy:Y(acac)(3)(phen), Dy:Y(hfa)(3)(DPEPO), Dy:Y(4-BBA)(3)(TPPO), Dy:Y(acac)(3), and Dy:Y(acac)(3)(DPEPO), where the Dy/Y ratio is 1:9. We characterize the materials' photoluminescence at different temperatures to determine the TCT calibration parameters and the degree to which thermal quenching influences the emission. From this data we observe a link between the excited state lifetime at room temperature and the degree to which the material is susceptible to thermal quenching (i.e. materials having long room temperature lifetimes are more resistant to thermal quenching than materials with short room temperature lifetimes). Of the five complexes tested we find that Dy:Y(acac)(3)(DPEPO) has the best thermal performance, with the most likely source of improvement being DPEPO's compact rigid structure. This rigidity helps with energy transfer to the Dy3+ ion, suppresses non-radiative loss modes, and reduces exciplex formation.
Metrics
6 Record Views
Details
- Title
- Dy3+-doped yttrium complex molecular crystals for two-color thermometry in heterogeneous materials
- Creators
- Benjamin R. Anderson - Washington State Univ, Appl Sci Lab, Inst Shock Phys, Spokane, WA 99210 USARay Gunawidjaja - Washington State UniversityHergen Eilers - Washington State University
- Publication Details
- Journal of luminescence, Vol.188, pp.238-245
- Academic Unit
- Institute for Shock Physics
- Publisher
- Elsevier
- Number of pages
- 8
- Grant note
- FA9550-15-1-0309 / Air Force Office of Scientific Research; United States Department of Defense; Air Force Office of Scientific Research (AFOSR)
- Identifiers
- 99900876939801842
- Language
- English
- Resource Type
- Journal article