Journal article
[FeFe]‐Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes
Angewandte Chemie (International ed.), Vol.47(50), pp.9756-9759
12/01/2008
Handle:
https://hdl.handle.net/2376/106749
PMID: 19003843
Abstract
Super model: Diiron dithiolates exist in nature in [FeFe]‐hydrogenase, for the purpose of making or oxidizing molecular hydrogen. Evidence for how H2 interacts with diiron complexes has been realized using model diiron dithiolato carbonyl complexes. The pathway for this interaction has been elucidated computationally as well as synthetically, by using silanes in place of H2.
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Details
- Title
- [FeFe]‐Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes
- Creators
- Zachariah M HeidenGiuseppe ZampellaLuca De GioiaThomas B Rauchfuss
- Publication Details
- Angewandte Chemie (International ed.), Vol.47(50), pp.9756-9759
- Academic Unit
- Chemistry, Department of
- Publisher
- WILEY‐VCH Verlag; Weinheim
- Number of pages
- 4
- Grant note
- National Institutes of Health
- Identifiers
- 99900546987401842
- Language
- English
- Resource Type
- Journal article