Journal article
Isolation of electronic from geometric contributions to Bergman cyclization of metalloenediynes
Chemical communications (Cambridge, England), Vol.9(10), pp.1156-1157
05/21/2003
Handle:
https://hdl.handle.net/2376/104806
PMID: 12778712
Abstract
Conformationally constrained ethylene-diamine metalloenediyne compounds exhibit alkyne termini separations that are constant and independent of metal center geometry. Ancillary chloride ligand electron donation into the Bergman cyclization reaction coordinate, however, dramatically influences the observed temperatures.
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Details
- Title
- Isolation of electronic from geometric contributions to Bergman cyclization of metalloenediynes
- Creators
- Sibaprasad Bhattacharyya - Department of Chemistry, Indiana University, Bloomington, IN, USAAurora E ClarkMaren PinkJeffrey M Zaleski
- Publication Details
- Chemical communications (Cambridge, England), Vol.9(10), pp.1156-1157
- Academic Unit
- Chemistry, Department of
- Publisher
- England
- Grant note
- R01-GM62541-01A1 / NIGMS NIH HHS
- Identifiers
- 99900546849101842
- Language
- English
- Resource Type
- Journal article