Journal article
Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3
Chemical communications (Cambridge, England), Vol.47(20), pp.5729-5731
05/28/2011
Handle:
https://hdl.handle.net/2376/106475
PMID: 21503337
Abstract
Reductions of chiral ketimines effected under H(2) by catalytic amounts of B(C(6)F(5))(3) result in moderate to excellent diastereoselectivities. In the case of camphor and menthone derived imines, the reductions proceeded with greater than 95% diastereoselectivity.
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Details
- Title
- Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3
- Creators
- Zachariah M Heiden - Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6Douglas W Stephan
- Publication Details
- Chemical communications (Cambridge, England), Vol.47(20), pp.5729-5731
- Academic Unit
- Chemistry, Department of
- Publisher
- England
- Identifiers
- 99900546827401842
- Language
- English
- Resource Type
- Journal article