Journal article
Monitoring lignocellulosic bioethanol production processes using Raman spectroscopy
Bioresource technology, Vol.172, pp.112-120
11/2014
Handle:
https://hdl.handle.net/2376/106100
PMID: 25255187
Abstract
Process control automation in the emerging biorefinery industry may be achieved by applying effective methods for monitoring compound concentrations during the production processes. This study examines the application of Raman spectroscopy with an excitation wavelength of 785nm and an immersion probe for in situ monitoring the progression of pretreatment, hydrolysis and fermentation processes in the production of lignocellulosic ethanol. Raman signals were attenuated by light scattering cells and lignocellulosic particulates, which the quantification method to some degree could correct for by using an internal standard in the spectra. Allowing particulates to settle by using a slow stirring speed further improved results, suggesting that Raman spectroscopy should be used in combination with continuous separation when used to monitor process mixtures with large amounts of particulates. The root mean square error of prediction (RMSE) of ethanol and glucose measured in real-time was determined to be 0.98g/L and 1.91g/L respectively.
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Details
- Title
- Monitoring lignocellulosic bioethanol production processes using Raman spectroscopy
- Creators
- Jens A Iversen - Section for Sustainable Biotechnology, Aalborg University, A.C. Meyers Vænge 15, 2450 Copenhagen SV, Denmark; Center for Bioproducts and Bioenergy, Washington State University Tri-Cities, 2710 Crimson Way, Richland, WA 99354, USABirgitte K Ahring - Section for Sustainable Biotechnology, Aalborg University, A.C. Meyers Vænge 15, 2450 Copenhagen SV, Denmark; Center for Bioproducts and Bioenergy, Washington State University Tri-Cities, 2710 Crimson Way, Richland, WA 99354, USA. Electronic address: bka@wsu.edu
- Publication Details
- Bioresource technology, Vol.172, pp.112-120
- Academic Unit
- Chemical Engineering and Bioengineering, School of
- Publisher
- England
- Identifiers
- 99900546943501842
- Language
- English
- Resource Type
- Journal article