Journal article
One-step acrylation of soybean oil (SO) for the preparation of SO-based macromonomers
Green chemistry : an international journal and green chemistry resource : GC, Vol.15(3), pp.641-645
03/01/2013
Handle:
https://hdl.handle.net/2376/101523
Abstract
In this work, a novel efficient one-step method for preparation of acrylated soybean oil (ASO) was introduced. ASO was obtained by reacting soybean oil (SO) and acrylic acid (AA) directly under the catalysis of BF
3
·Et
2
O. Effects of reaction stoichiometry and reaction time on the conversion of the double bonds of SO were studied.
1
H NMR analysis indicated that the number of acrylate groups could reach 3.09 per triglyceride molecule or the conversion of the double bonds was up to ∼75.7%. Copolymerization of the ASO and styrene was demonstrated, and the flexural and dynamic mechanical properties of the resulting polymers were evaluated.
Acrylated soybean oil (ASO) was synthesized by reacting soybean oil (SO) and acrylic acid under the catalysis of BF
3
·Et
2
O, and was copolymerized with styrene to obtain crosslinked polymers.
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Details
- Title
- One-step acrylation of soybean oil (SO) for the preparation of SO-based macromonomers
- Creators
- Pei ZhangJinwen Zhang
- Publication Details
- Green chemistry : an international journal and green chemistry resource : GC, Vol.15(3), pp.641-645
- Academic Unit
- Composite Materials and Engineering Center
- Number of pages
- 5
- Identifiers
- 99900546561001842
- Language
- English
- Resource Type
- Journal article