Journal article
Segregation of solute atoms to interphase boundaries in GdNi2
Hyperfine interactions, Vol.238(1), pp.1-11
01/11/2017
Handle:
https://hdl.handle.net/2376/121554
Abstract
Lattice locations of 111 In impurity probe atoms in intermetallic GdNi 2 were studied as a function of alloy composition and temperature using perturbed angular correlation spectroscopy (PAC). Measurements were made on a pair of samples that were richer and poorer in Gd. Three nuclear quadrupole interaction signals were detected and their equilibrium site fractions were measured up to 700 ∘ C. Two signals have well-defined electric field gradients (EFGs) and are attributed to In-probes on Gd- and Ni-sites in a well-ordered lattice.A third signal exhibiting strong inhomogeneous broadening was observed at low temperature in Gd-richer samples. This is attributed to segregation of the In-probes to phase boundaries (PB) of minor volume fractions of the neighboring GdNi phase. A measurement made on a stoichiometric GdNi sample exhibited the same inhomogeneously broadened signal, indicating that In-probes prefer to occupy PB and/or grain boundary sites in GdNi rather than the well-defined Gd- and Ni-sites. Changes in site fractions were reversible above 300 ∘ C, indicating that probe atoms equilibrate among all lattice locations within a time period of one day. Thus, PB sites provide lower enthalpy environments for In-probes than either crystallographic site in GdNi 2 . Enthalpy differences between the levels were determined from measurements of temperature dependences of ratios of site fractions. The enthalpy of transfer of In-probes from the Gd- to Ni-sublattice, which is coupled to intrinsic disorder in the compound, was found to be much smaller in the Gd-richer sample than in the Gd-poorer sample. This can be explained by differing temperature dependences of intrinsic defect concentrations at the two compositions. Among those probes that remain within the GdNi 2 phase, there is a temperature dependence of the ratio of site fractions of In-probes on Gd- and Ni-sites. Taking this into account, a macroscopic segregation enthalpy is derived from the measurements. Additionally, brief measurements on GdNi 2 samples doped
Metrics
10 Record Views
Details
- Title
- Segregation of solute atoms to interphase boundaries in GdNi2
- Creators
- Ryan Murray - Washington State UniversityDebashis Banerjee - Washington State UniversityGary S Collins - Washington State UniversityMatthew O Zacate - Northern Kentucky University
- Publication Details
- Hyperfine interactions, Vol.238(1), pp.1-11
- Academic Unit
- Physics and Astronomy, Department of
- Publisher
- Springer International Publishing
- Grant note
- DMR 14-10159 / National Science Foundation (http://dx.doi.org/10.13039/100000001)
- Identifiers
- 99900647240801842
- Language
- English
- Resource Type
- Journal article