Journal article
Subduction controls of Hf and Nd isotopes in lavas of the Aleutian island arc
Earth and planetary science letters, Vol.300(3), pp.226-238
2010
Handle:
https://hdl.handle.net/2376/110594
Abstract
The Hf and Nd isotopic compositions of 71 Quaternary lavas collected from locations along the full length of the Aleutian island arc are used to constrain the sources of Aleutian magmas and to provide insight into the geochemical behavior of Nd and Hf and related elements in the Aleutian subduction–magmatic system. Isotopic compositions of Aleutian lavas fall approximately at the center of, and form a trend parallel to, the terrestrial Hf–Nd isotopic array with
ε
Hf of +
12.0 to +
15.5 and
ε
Nd of +
6.5 to +
10.5. Basalts, andesites, and dacites within volcanic centers or in nearby volcanoes generally all have similar isotopic compositions, indicating that there is little measurable effect of crustal or other lithospheric assimilation within the volcanic plumbing systems of Aleutian volcanoes. Hafnium isotopic compositions have a clear pattern of along-arc increase that is continuous from the eastern-most locations near Cold Bay to Piip Seamount in the western-most part of the arc. This pattern is interpreted to reflect a westward decrease in the subducted sediment component present in Aleutian lavas, reflecting progressively lower rates of subduction westward as well as decreasing availability of trench sediment. Binary bulk mixing models (sediment
+
peridotite) demonstrate that 1–2% of the Hf in Aleutian lavas is derived from subducted sediment, indicating that Hf is mobilized out of the subducted sediment with an efficiency that is similar to that of Sr, Pb and Nd. Low published solubility for Hf and Nd in aqueous subduction fluids lead us to conclude that these elements are mobilized out of the subducted component and transferred to the mantle wedge as bulk sediment or as a silicate melt. Neodymium isotopes also generally increase from east to west, but the pattern is absent in the eastern third of the arc, where the sediment flux is high and increases from east to west, due to the presence of abundant terrigenous sediment in the trench east of the Amlia Fracture Zone, which is being subducting beneath the arc at Seguam Island. Mixing trends between mantle wedge and sediment end members become flatter in Hf–Nd isotope space at locations further west along the arc, indicating that the sediment end member in the west has either higher Nd/Hf or is more radiogenic in Hf compared to Nd. This pattern is interpreted to reflect an increase in pelagic clay relative to the terrigenous subducted sedimentary component westward along the arc. Results of this study imply that Hf does not behave as a conservative element in the Aleutian subduction system, as has been proposed for some other arcs.
► Hf and Nd isotope ratios in Aleutian lavas increase east-to-west along the arc. ► Along-arc increases in Hf and Nd isotopes are controlled by sediment subduction rates. ► 1-2% of Hf in most Aleutian lavas is derived from subducted sediment. ► The role of pelagic clay subduction appears to increase (east-to-west) along the arc. ► Assimilation of arc crust has little measureable effect on Hf and Nd in Aleutian lavas.
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Details
- Title
- Subduction controls of Hf and Nd isotopes in lavas of the Aleutian island arc
- Creators
- G.M Yogodzinski - Department of Earth & Ocean Sciences, University of South Carolina, 701 Sumter St., EWSC617, Columbia, SC 29208, United StatesJ.D Vervoort - School of Earth & Environmental Sciences, Washington State University, P.O. Box 642812 Pullman, WA 99164-6376, United StatesS.T Brown - Department of Earth & Ocean Sciences, University of South Carolina, 701 Sumter St., EWSC617, Columbia, SC 29208, United StatesM Gerseny - School of Earth & Environmental Sciences, Washington State University, P.O. Box 642812 Pullman, WA 99164-6376, United States
- Publication Details
- Earth and planetary science letters, Vol.300(3), pp.226-238
- Academic Unit
- Environment, School of the (CAS)
- Publisher
- Elsevier B.V
- Identifiers
- 99900547494301842
- Language
- English
- Resource Type
- Journal article